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Polymers of unidimentional coordination [M(sac)2(H2O)(pyz)]n, (M= Ni2+, Cu2+ and Zn2+, sac =saccharinate, pyz= pyrazine), spectroscopy and magnetic properties
Coordination polymers have been prepared by the hydrothermal reaction of M2+saccharinates (M = Ni, Cu and Zn) and pyrazine, pyz, in a ratio 1:1. The complexes of formula [M(sac)2(H2O)2pyz]n, M = Ni2+ and Zn2+ and ...
Síntesis y caraterización del ligando tris-(2-tiosalicilamidoetil)amina y sus complejos de hierro e indio
The coordination chemistry of the hexadentate ligand, tris(2-thiosalicylamidoethyl)amine, (LH3), was studied. The reaction of the ligand trianion with iron(III) and indium(III) yields monomeric hexacoordinate complexes, ...
SYNTHESIS, CHARACTERIZATION AND REDOX BEHAVIOUR OF MIXED LIGAND COPPER(II) SACCHARINATE COMPLEXES
Synthesis, characterization and redox behaviour of mixed ligand copper(II) saccharinate complexes
Three mixed-ligand complexes of Cu(II) with saccharin (sac), pyrazole, (Hpz), imidazole, (Himid) were synthesized and characterized on the basis of elemental analysis, FT-IR spectroscopy, magnetic susceptibility, EPR ...