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Polymers of unidimentional coordination [M(sac)2(H2O)(pyz)]n, (M= Ni2+, Cu2+ and Zn2+, sac =saccharinate, pyz= pyrazine), spectroscopy and magnetic properties
Coordination polymers have been prepared by the hydrothermal reaction of M2+saccharinates (M = Ni, Cu and Zn) and pyrazine, pyz, in a ratio 1:1. The complexes of formula [M(sac)2(H2O)2pyz]n, M = Ni2+ and Zn2+ and ...
SYNTHESIS, CHARACTERIZATION AND REDOX BEHAVIOUR OF MIXED LIGAND COPPER(II) SACCHARINATE COMPLEXES
Synthesis, characterization and redox behaviour of mixed ligand copper(II) saccharinate complexes
Three mixed-ligand complexes of Cu(II) with saccharin (sac), pyrazole, (Hpz), imidazole, (Himid) were synthesized and characterized on the basis of elemental analysis, FT-IR spectroscopy, magnetic susceptibility, EPR ...
Síntesis y caraterización del ligando tris-(2-tiosalicilamidoetil)amina y sus complejos de hierro e indio
The coordination chemistry of the hexadentate ligand, tris(2-thiosalicylamidoethyl)amine, (LH3), was studied. The reaction of the ligand trianion with iron(III) and indium(III) yields monomeric hexacoordinate complexes, ...