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Reactivity and structure of derivatives of 2-hydroxy-1,4-naphthoquinone (lawsone)
The structures of two derivatives of 2-hydroxy-1,4-naphthoquinone (lawsone) are examined using the density functional theory (DFT) hybrid functional B3LYP. Using the optimized structure of lawsone acetate, the reactivity ...
Structure, chirality, and field testing of a male-produced aggregation pheromone of Asian palm weevilRhynchophorus bilineatus (Montr.) (Coleoptera: Curculionidae)
4-Methyl-5-nonanol is a male-produced aggregation pheromone of the Asian palm weevil,Rhynchophorus bilineatus (Montr.). The pheromone was identified by coupled gas chromatographic-electroantennographic detection (GC-EAD) ...
Sex pheromone components of Diatraea considerata (Heinrich) (Lep., Pyralidae)
Three aldehydes. (Z)-11-hexadecenal (Z11–16:Ald), (Z)-7-hexadecenal (Z7–16:Ald) and (Z)-13-octadecenal (Z13–18:Ald), in a ratio of 74:23:3 are female-produced sex pheromone components of the pyralid moth, Diatraea considerata ...
Sudoku Puzzles for First-Year Organic Chemistry Students
We use sudoku puzzles to help the students (i) learn the correspondence between the names of the amino acids, their abbreviations, and codes and (ii) learn the correspondence between the names of the functional groups, ...
Synthesis of 2-hydroxy-3-substituted naphthoquinones using the Heck reaction
An efficient Heck coupling of 2-hydroxy-3-iodo-naphthoquinone with a series of electron-deficient alkenes in aqueous solution has been accomplished. The method is characterized by simple conditions and facile work-up to ...
Efficient syntheses of streptocarpone and (±)-a-dunnione
An efficient divergent synthesis of both streptocarpone and racemic α-dunnione from lawsone are described. A one-pot, formal [3+2] cyclization to form a furanonaphthoquinone directly provided a common intermediate.
Pheromone chirality of african palm weevil, Rhynchophorus phoenicis (F.) and palmetto weevil, Rhynthophorus crueniatus (F.) (Coleoptera: Curculionidae)
There are four stereoisomers of both 3-methyl-octan-4-ol, the aggregation pheromone of the African palm weevil,Rhynchophorus phoenicis (F.) and 5-methyl-octan-4-ol, the aggregation pheromone of the palmetto weevil,Rhynchophorus ...
Ethyl propionate: Synergistic kairomone for african palm weevil,Rhynchophorus phoenicis L. (Coleoptera: Curculionidae)
Small trunk pieces of a freshly felled 10-year-old oil palm,Elaeis quineensis (Jacq.), were placed in a modified Nalgene desiccator, and volatiles captured for six days on Porapak Q. Gas chromatographic (GC) analysis of ...
Aggregation Pheromone of Palm Weevil, Dynamis borassi
4-Methyl-5-nonanol (1) is the male-produced aggregation pheromone of the palm weevil, Dynamis borassi (F.) from Colombia. The pheromone was identified by coupled gas chromatographic–electroantennographic detection (GC-EAD) ...
Synthesis and biological evaluation of novel ferrocene–naphthoquinones as antiplasmodial agents
This work deals with the synthesis and evaluation of new compounds designed by combination of 1,4-naphthoquinone and ferrocene fragments in a 3-ferrocenylmethyl-2-hydroxy-1,4-naphthoquinone arrangement. A practical coupling ...