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dc.creatorLedezma Gairaud, Marisol
dc.creatorPineda Cedeño, Leslie William
dc.creatorAromí, Guillem
dc.creatorSañudo, E. Carolina
dc.date.accessioned2018-12-20T15:43:57Z
dc.date.available2018-12-20T15:43:57Z
dc.date.issued2013-11
dc.identifier.citationhttps://www.sciencedirect.com/science/article/pii/S0277538713001113?via%3Dihub#!es_ES
dc.identifier.issn0277-5387
dc.identifier.urihttp://hdl.handle.net/10669/76361
dc.description.abstractFollowing our interest in microwave assisted synthesis in coordination chemistry; we report here the results of the study of a mixed metal Mn/Ni system under common bench-top conditions and using the microwave reactor. Using bench-top, the mixed metal Mn/Ni complex Mn5Ni4(OH)4(C5H12NO)4(SALOH)6(SALO)4] (complex 1) is obtained while the microwave reactor affords a Mn7 complex, [Mn7(OH)3(C5H12NO)2(C5H13NO)(SALO)6(SALOH)3] complex 2, where the Ni(II) has not been incorporated or a Mn2Ni2 cubane, [Pr2NH2][Mn2Ni2(OH)2(C5H12NO)2(SALO)3(SALOH)2] complex 3. Graphical abstract Following our interest in microwave assisted synthesis in coordination chemistry; we report here the results of the study of a mixed metal Mn/Ni system under common bench-top conditions and using the microwave reactor. Using bench-top, the mixed metal Mn/Ni complex [Mn5Ni4(OH)4(C5H12NO)4(SALOH)6(SALO)4] (complex 1) is obtained while the microwave reactor affords a Mn7 complex, [Mn7(OH)3(C5H12NO)2(C5H13NO)(SALO)6(SALOH)3] complex 2, where the Ni(II) has not been incorporated or a Mn2Ni2 cubane, [Pr2NH2][Mn2Ni2(OH)2(C5H12NO)2(SALO)3(SALOH)2] complex 3.es_ES
dc.description.sponsorshipUniversidad de Costa Rica/[115-B1-168]/UCR/Costa Ricaes_ES
dc.description.sponsorshipGobierno español/[CTQ2009-06959]//Españaes_ES
dc.language.isoen_USes_ES
dc.relation.ispartof
dc.sourcePolyhedron, vol. 64(12), pp. 45-51es_ES
dc.subjectMagnetismes_ES
dc.subjectMicrowave assisted synthesises_ES
dc.subjectCoordination chemistryes_ES
dc.subjectGeorge Christou 60th birthday special issuees_ES
dc.subject543.085 82 Espectroscopia de microondases_ES
dc.titleMicrowave assisted synthesis: A Mn/Ni reaction system affording Mn5Ni4, Mn2Ni2 and Mn7 complexeses_ES
dc.typeinfo:eu-repo/semantics/articlees_ES
dc.date.updated2018-12-13T20:24:16Z
dc.identifier.doi10.1016/j.poly.2013.02.018
dc.description.procedenceUCR::Investigación::Unidades de Investigación::Ciencias Básicas::Centro de Investigación en Electroquímica y Energía Química (CELEQ)es_ES
dc.description.procedenceUCR::Docencia::Ciencias Básicas::Facultad de Ciencias::Escuela de Químicaes_ES
dc.identifier.codproyecto115-B1-168


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