1,3-Bis{[(2,6-di­methyl­phen­yl)sulfan­yl]meth­yl}benzene

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Fecha

2019

Autores

Garita Salazar, Bruno
Pineda Cedeño, Leslie William

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Resumen

The structure of the title compound, C24H26S2, an example of a pincer ligand with an SCS-chelation motif, illustrates the steric effects of the methyl groups in the thio­phenyl rings at the 2- and 6-positions, forcing a dissimilar spatial orientation of the thio­phenyl rings relative to the central aryl group [dihedral angles = 33.58 (7) and 40.49 (7)°]. In the crystal, weak S⋯S contacts [3.4009 (7) Å] link the mol­ecules into inversion dimers.

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Palabras clave

Ligandos pinza, Azufre, Efecto quelato, Estabilización cinética, Crystal structure, Chelating ligand, SCS pincer ligands, Kinetic stabilization, Sulfur atom

Citación

https://iucrdata.iucr.org/x/issues/2019/05/00/hb4295/index.html

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